Thermodynamic analysis of Fe and Mg partitioning between plagioclase and silicate liquid

 Thermodynamic analysis of Fe- and Mg-bearing plagioclase and silicate liquid was carried out based on reported element partitioning data between plagioclase and silicate liquid in reduced conditions, solution properties of ternary feldspar, standard state properties of plagioclase endmembers and solution properties of multicomponent silicate liquid. Derived mixing properties of Fe- and Mg-bearing plagioclase are in harmony with estimated results from synthetic experiments in the systems CaAl₂Si₂O₈-CaFeSi₃O₈ and CaAl₂Si₂O₈-CaMgSi₃O₈. Based on the determined solution properties of the plagioclase, a computer program to calculate the element partition relationships between Fe- and Mg-bearing plagioclase and multicomponent silicate liquid was developed. The FeO, MgO and MgO/(MgO + FeO) in plagioclase predicted from known liquid compositions and pressure are in agreement with measurements within 0.2 wt%, 0.1 wt% and 0.1 (mol ratio), respectively. The Fe³⁺ content in plagioclase crystallized at high oxygen fugacity can be estimated with this program. The Fe³⁺/total Fe ratio in plagioclase crystallized near the quartz-fayalite-magnetite buffer ranges from 0 to 0.5, which is consistent with previous study on natural plagioclase in submarine basalt. Derived solution properties of the Fe- and Mg-bearing plagioclase are also used to calculate equilibrium composition relationship between olivine and plagioclase. Change of X _Fo in olivine coexisting with plagioclase affects MgO and FeO contents in plagioclase greatly. The present model predicts X _Fo of coexisting olivine from the chemical composition of plagioclase to ±0.1 accuracy at given pressure and temperature. Received: 27 March 1998 / Accepted: 30 September 1999     

Northward cooling of the Kuncha nappe and downward heating of the Lesser Himalayan autochthon distributed to the south of Mt. Annapurna,western central Nepal

We investigated the tectonothermal history of the Lesser Himalayan sediments (LHS), which are tectonically overlain by the Higher Himalayan Crystalline. Fission‐track dating and the track length measurement of detrital zircons obtained from the Kuncha nappe and the Lesser Himalayan autochthonous sediments in western central Nepal revealed northward cooling of the nappe and possible downward heating of the autochthon by the overlying hot nappe. Nine zircon fission‐track (ZFT) ages of the nappe showed northward‐younging linear distribution from 11.6 Ma in the front at Tamghas, 6 Ma in the central at Naudanda, and 1.6 Ma in the northernmost point at Tatopani. Thermochronological invert calculation of the ZFT length elucidated that the Kuncha nappe gradually cooled down (30 °C/Myr) at the front and rapidly cooled down (120 °C/Myr) at the root zone. In contrast, the ZFT age of the Chappani Formation, located just beneath the Kuncha nappe in the central part, demonstrated a totally reset age of 6.8 Ma, whereas the Virkot Formation, structurally far from the nappe, yielded a partially reset age of 457.3 Ma. This suggests that the LHS underwent downward heating, resulting in a thermal print on the upper part of the LHS; however, the thermal effect was not sufficient to anneal ZFT totally in the deeper part. Presently, the nappe cover is eroded and denuded from this area. Detrital zircons from the Chappani Formation in Tansen area to the south of the Bari Gad Fault did not show any evidence of annealing, suggesting that nappe never covered the LHS distributed to the south of the fault.     

Northward younging zircon fission‐track ages from 13 to 2 Ma in the eastern extension of the Kathmandu nappe and underlying Lesser Himalayan sediments distributed to the south of Mt. Everest

This study is concerned with the tectono‐thermal history of the Kathmandu nappe and the underlying Lesser Himalayan sediments (LHS) that are distributed in eastern Nepal. We carried out zircon fission‐track(ZFT) dating and obtained 16 ZFT ages from the eastern extension of the Kathmandu nappe, the Higher Himalayan Crystalline, Kuncha nappe, and the Main Central Thrust (MCT) zone. The ZFT ages of the frontal part of the Kathmandu nappe range from 13.0 ±0.8 Ma to 10.7 ±0.7 Ma and exhibit a northward‐younging tendency. These Middle Miocene ZFT ages indicate that the frontal part of the Kathmandu nappe remained at a temperature above 240 °C until the termination of its southward emplacement at 12–11 Ma. The ZFT ages of the LHS range from 11.1 ±0.9 Ma in the southern part of the Okhaldhunga Window to 2.4 ±0.3 Ma of the augen gneiss in the northern margin and also exhibit a northward‐younging age distribution. The ZFT ages show the northward‐younging linear distribution pattern (?0.16 Ma/km) along the across‐strikesection from the frontal part of the Kathmandu nappe to the root zone, without a significant age gap. This distribution pattern indicates that the Kathmandu nappe, the underlying MCT zone, and the Kuncha nappe cooled from the frontal zone to the root zone as a thermally united geologic body at a temperature below 240 °C. An older ZFT age (456.3 ±24.3 Ma), which was partially reset at the axial part of the Midland anticlinorium in the central part of the Okhaldhunga Window, was explained by downward heating from the “hot” Kathmandu nappe. The above evidence supported a model that southward emplacement of the hot Kathmandu nappe resulted in a thermal imprint on the upper part of the LHS; however, the lower part did not reach 240 °C.     

Postglacial stratigraphic evolution of a current-influenced sandy shelf: offshore Kujukuri strandplain,central Japan

Sandy shelf sediments are important elements of clastic sedimentary systems because of their wide distribution in the geological record and their significance as hydrocarbon reservoirs. Although many studies have investigated shelf sediments influenced by waves or tidal currents, little is known about shelf sediments influenced by oceanic currents, particularly their lithofacies characteristics and stratigraphic evolution. This study investigated the stratigraphic evolution of shelf sediments off the Kujukuri strandplain facing the Pacific Ocean, which is influenced by the strong Kuroshio Current. Sediment cores were obtained from six locations on the Kujukuri shelf (34 to 124 m water depth) using a vibrocorer. The dominant lithofacies is mud-free sand with low-angle cross-lamination associated with alternating beds of finer and coarser sand with cross-lamination. These display depositional processes influenced by storm waves and the Kuroshio Current, respectively. This finding is consistent with the previously presented modern and historical observations of the Kuroshio Current and estimates of the storm-wave base. Radiocarbon dates show that the sediment succession formed during the last transgressive and highstand stages after 13·1 ka. The depositional processes during the stages represent a transition from storm waves with abundant sediment supply to both storm waves and the Kuroshio Current with sediment starvation mainly due to its trapping in the strandplain. Comparison to other Holocene–Modern shelf systems suggests that the sandy shelf successions are strongly influenced by oceanic currents under conditions of limited riverine input and open coastal geometry. The resultant sand-dominated succession is characterized by reversal of the proximal to distal grain-size trend compared to the fining for most other recognized wave/storm-dominated shelf successions. This is because of seaward increase in the influence of the Kuroshio Current. Thus, shelf deposits are naturally complex, and these may be further complicated by the additional influence of oceanic currents above the usual wave-dominated and tide-dominated end members.     

Satellite Navigation and Geospatial Awareness: Long-Term Effects of Using Navigation Tools on Wayfinding and Spatial Orientation

This article examined long-term effects of using navigation tools on wayfinding and spatial orientation, through a survey analysis of the experience of using navigation tools and spatial aptitudes, and a behavioral experiment of real-world navigation. Experience of tool use was measured in terms of regular use (time length and frequency) and accumulated experience (time length multiplied by frequency). The survey analysis showed that frequent users of pedestrian navigation systems tended to be low on sense of direction and mental rotation. In contrast, longtime users of maps tended to be high on sense of direction and favor survey navigation strategies. The behavioral experiment showed that people who had more accumulated experience of using in-car navigation systems traveled less efficiently and learned the configurations of traveled routes less accurately with a mobile tool and a paper map. The analysis of long-term effects through structural equation modeling showed that spatial aptitudes and accumulated experience of tool use independently affect wayfinding and spatial orientation and that the negative effects of accumulated experience were larger than the positive effects of spatial aptitudes. The results and implications are discussed in relation to existing studies of short-term effects and spatial thinking.     

Upper Mantle Velocity Structure Estimated From Ps-Converted Wave Beneath the North-Eastern Japan Arc

Summary. The upper boundary of the descending oceanic plate is located by using PS -waves (converted from P to S at the boundary) in the Tohoku District, the north-eastern part of Honshu, Japan. the observed PS-P time data are well explained by a two-layered oceanic plate model composed of a thin low-velocity upper layer whose thickness is less than 10 km and a thick high-velocity lower layer; the upper and lower layers respectively have 6 per cent lower and 6 per cent higher velocity than the overriding mantle. the estimated location of the upper boundary is just above the upper seismic plane of the double-planed deep seismic zone. This result indicates that events in the upper seismic plane, at least in the depth range from 60 to 150 km, occur within the thin low-velocity layer on the surface of the oceanic plate.     

Motion of iron sulfide inclusions inside a shock‐melted chondrule

Abstract— We calculated the trajectories of molten spheres of iron sulfide inclusions inside a melted chondrule during the nebular shock wave heating. Our calculations included the effects of high‐velocity internal flow in the melted chondrule and apparent gravitational force caused by the drag force of nebular gas flow. The calculated results show that large iron sulfide inclusions, which have radii 0.23 times larger than those of the parent chondrules, must reach the surface of the melted chondrule within a short period of time (<<1 s). This effect will provide us with very important information about chondrule formation by nebular shock wave heating.     

Relationship between atmospheric conditions at Dhaka, Bangladesh, and rainfall at Cherrapunjee, India

To improve flood forecasting, the understanding of the atmospheric conditions associated with severe rainfall is crucial. We analysed the atmospheric conditions at Dhaka, Bangladesh, using upper-air soundings. We then compared these conditions with daily rainfall variations at Cherrapunjee, India, which is a main source of floodwater to Bangladesh, and a representative sample of exceptionally heavy rainfall events. The analysis focussed on June and July 2004. June and July are the heaviest rainfall months of the year at Cherrapunjee. July 2004 had the fourth-heaviest monthly rainfall of the past 31 years, and severe floods occurred in Bangladesh. Active rainfall periods at Cherrapunjee corresponded to “breaks” in the Indian monsoon. The monsoon trough was located over the Himalayan foothills, and strong westerly winds dominated up to 7 km at Dhaka. Near-surface wind below 1 km had southerly components, and the wind profile had an Ekman spiral structure. The results suggest that rainfall at Cherrapunjee strongly depends on the near-surface wind speed and wind direction at Dhaka. Lifting of the near-surface southerly airflow by the Meghalaya Plateau is considered to be the main contributor to severe rainfall at Cherrapunjee. High convective available potential energy (CAPE) also contributes to intense rainfall.